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Geochemical approaches to the quantification of dispersed volcanic ash in marine sediment
Progress in Earth and Planetary Sciencevolume 3, Article number: 1 (2016)
Volcanic ash has long been recognized in marine sediment, and given the prevalence of oceanic and continental arc volcanism around the globe in regard to widespread transport of ash, its presence is nearly ubiquitous. However, the presence/absence of very fine-grained ash material, and identification of its composition in particular, is challenging given its broad classification as an “aluminosilicate” component in sediment. Given this challenge, many studies of ash have focused on discrete layers (that is, layers of ash that are of millimeter-to-centimeter or greater thickness, and their respective glass shards) found in sequences at a variety of locations and timescales and how to link their presence with a number of Earth processes. The ash that has been mixed into the bulk sediment, known as dispersed ash, has been relatively unstudied, yet represents a large fraction of the total ash in a given sequence. The application of a combined geochemical and statistical technique has allowed identification of this dispersed ash as part of the original ash contribution to the sediment. In this paper, we summarize the development of these geochemical/statistical techniques and provide case studies from the quantification of dispersed ash in the Caribbean Sea, equatorial Pacific Ocean, and northwest Pacific Ocean. These geochemical studies (and their sedimentological precursors of smear slides) collectively demonstrate that local and regional arc-related ash can be an important component of sedimentary sequences throughout large regions of the ocean.
In the modern era, marine scientists’ interest in volcanic ash can be traced back at least to the HMS Challenger expedition (1872–1876). Indeed, “What is marine sediment made of?” is a question that has been asked for 100s of years, and while many aspects of the petrology, mineralogy, and geochemistry of marine sediment have been well characterized, it is remarkable how much remains unknown about some key aspects of ocean mud. In particular, the presence/absence and composition of volcanic ash is challenging given its fine grain size, broad classification as an “aluminosilicate”, and common presence, especially since both oceanic and continental arc volcanism are often located physically adjacent to oceanic environments and are known to globally generate and transport widespread ash (Fig. 1). Certainly, civilization’s natural curiosity about volcanism has driven interest in the marine records of ash for generations of scientists. Additionally, these studies considered how to link their presence with explosive volcanism, climate, arc evolution, biological productivity, and other geological processes, as described below. Although the term “ash” is normally used in volcanology as a grain size definition (32 μm to 2 mm, e.g., Fisher and Schmincke 1984) for explosive volcanic products (juvenile matter and lithic fragments), we here use the term “ash” to indicate a product (mostly volcanic glass) from explosive volcanism no matter which grain size a particle may have. Therefore, in this paper we refer to “discrete ash layers” as a volcanic product that is present as a clearly visible bed in the marine sediments (that is, ash layers of millimeter-to-centimeter or greater thickness, Fig. 2a–f) and their respective glass shards (Fig. 2g–l)) found in sequences at a variety of locations and timescales.
Less widely recognized than the discrete layers of ash is what has been referred to as “dispersed” ash. “Dispersed ash” is defined as volcanic ash material of various grain sizes (including single μm grains) that is mixed throughout the bulk sediment. This ash occurs in addition to the discrete ash layers. The presence of dispersed ash in the marine record has previously been relatively overlooked as it is difficult to identify petrographically due to its commonly extremely fine grain size (Rose et al. 2003, and references therein) and/or alteration to authigenic clay (Sigurdsson et al. 1997; Plank et al. 2000). Such alteration (e.g., Schacht et al. 2008) often results in fine-grained material that is unable to be differentiated from detrital terrigenous clay (non-ash, derived from land) on the basis of visual study alone.
Dispersed ash is the result from bioturbation of pre-existing discrete ash layers, the settling of airborne or subaqueous ash through the water column, transport by rivers and currents from terrestrially exposed ash deposits, and other processes (e.g., gravity flows). Because dispersed ash has often been only qualitatively addressed (e.g., via sedimentological smear slides), however it still plays as vital a role as discrete ash layers in many studies on multiple spatial and temporal scales, including (but not limited to) the following:
Ash plays an important role for geochemical budgets (e.g., “Subduction Factory”), in that studies of geochemical recycling will benefit from an increased understanding of both input (subduction) and output (volcanism) fluxes (e.g., Straub 1997, 2008; Plank and Langmuir 1998; Straub and Schmincke 1998; Bryant et al. 1999, 2003; Straub and Layne 2002, 2003a,b; Hauff et al. 2003; Straub et al. 2004; Stern et al. 2006; Plank et al. 2007; Scudder et al. 2009, 2014; Tamura et al. 2009; Völker et al. 2011, 2014; Freundt et al. 2014). The amount, distribution, and composition of ash in sediment speaks to inputs as well as outputs in the budget, namely, knowing how much ash is entering the Subduction Factory is important for understanding recycling of geological material. Additionally, the ash record in the sediment itself provides an archive of local, regional, and global magmatic evolution.
The marine repository of explosive volcanic eruptions is a vital record from which the geological history of arc evolution is recorded (e.g., Kennett et al. 1977; Ninkovich et al 1978; Sigurdsson et al. 1980, 2000; Huang 1980; Cambray et al. 1993, 1995; Lee et al. 1995; Bailey 1996; Peters et al. 2000; Straub 2003; Kutterolf et al. 2008a,b,c; Straub et al. 2009, 2010, 2015). An improved understanding of arc evolution has the potential to contribute significantly to knowledge regarding the birth, life, and death of arc magmatism. Furthermore, a full accounting of the ash record (that is, comparison of the dispersed ash record with that of the discrete layers) may provide information about arc evolution and erosional histories of landmasses. Studies of ash distribution are also vitally important to document risk associated with volcanic hazards.
Reconstructions of eruption intensities and atmospheric wind patterns have been based on grain size characteristics and inferred dispersal patterns of the ash found in discrete layers, both at sea and on land (e.g., Huang et al. 1973, 1975; Shaw et al. 1974; Ledbetter and Sparks 1979; Carey and Sigurdsson 1980, 2000; Carey and Sparks 1986; Reid et al. 1996; Rose et al. 2003; Carey et al. 2010). These finer particles are probably the main constituent of dispersed ash, and therefore documenting the distribution of dispersed ash will constrain inferences of the transport pathways of volcanic material.
The ability to quantify the amount of dispersed ash will increase knowledge of sedimentary physical properties (e.g., Peacock 1990; Kastner et al. 1991; Underwood and Pickering 1996; Chan and Kastner 2000; Saffer et al. 2008, 2012; Hüpers et al. 2015). Given that ash alters to clay in a hydration reaction, the amount of water bound in the sediment will increase, thus decreasing the shear strength of the mud. Additionally, the fluid budget of subducting sediment will be affected by these and, further, hydration/dehydration reactions. A quantification of the amount of dispersed ash will thus assist interpretation of physical properties of marine sediment and subduction zone modeling.
Volcanic ash and eolian dust input to the surface ocean contributes nutrients to the surface ocean and are thus important for understanding trace metal cycling, biological productivity, climate change, volcano-climate interactions, and allied biogeochemical studies (e.g., Huang et al. 1974; Shaw et al. 1974; Carey 1997; Frogner et al. 2001; Jones and Gislason 2008; Robock et al. 2009; Duggen et al. 2010; Olgun et al. 2011; Kutterolf et al. 2013; Metzner et al. 2014).
Ash is commonly altered on and/or in the seafloor by diagenesis. In addition to the research cited above, for example, in a historically classic study, Gardner et al. (1986) observed many thin, pale green laminae (PGL) in the sediment cored during Deep Sea Drilling Project (DSDP) Leg 90 (Lord Howe Rise), which they identified as bentonites resulting from discrete ash fallout events. They found the temporal distribution of the PGLs to be similar to that of the discrete layers and logically concluded the PGLs were merely altered ash. For dispersed ash, however, the alteration increases the complexity for the application of techniques based on sedimentological and physical separation (e.g., grain size or sequential leachings to arrive at an aluminosilicate “residue”), because a fine-grained altered aluminosilicate ash is difficult to distinguish from, for example, fine-grained aluminosilicate eolian dust. The geochemical techniques summarized in this review, however, will still identify these alteration products as part of the original ash contribution to the sediment. For example, Hein et al. (1978) showed that ash beds in the Bering Sea become more altered with burial and form bentonite layers. They also documented that the chemistry of the bentonite beds reflects the chemistry of the parent ash, and differentiated authigenic smectite, which forms from the in situ breakdown of glass in ash layers or glass shards dispersed throughout the sediment, from detrital smectite derived from subaerial breakdown of recycled volcanic debris.
The use of tephra as a stratigraphic and chronologic tool has a long and wide-ranging history (e.g., Cambray et al. 1995; Straub and Schmincke 1998; Lowe 2011) and we do not intend here to repeat those efforts. Rather, in this paper, we (a) present a review of previous geochemical approaches to quantify dispersed ash in the Caribbean Sea and equatorial Pacific Ocean, (b) provide a summary of recent work applying a combined geochemical and multivariate statistical technique to identify dispersed ash in the northwest Pacific Ocean, and (c) describe preliminary results moving toward a regional assessment of inputs to the western Pacific Ocean (Fig. 1). We include some areas of research that are currently unresolved as they are likely to provide further insight into the nature and distribution of this important component of marine sediment. While radiogenic isotopes have proven helpful in studies of dispersed ash and the very fine detrital component (e.g., Ziegler et al. 2008; Scudder et al. 2014), in this paper we focus on major, trace, and rare earth elements since they are more commonly used in the various regions we discuss.
Geochemical approaches: theory and practice
Composition is different from transport
A basic tenet of provenance research is that studies based on chemical, isotopic, or mineralogic composition, or many aspects of sedimentology (e.g., grain size), cannot alone infer the transport pathway (e.g., eolian vs. subaqueous transport) by which a grain of volcanic ash eventually becomes entrained in the sediment. Strictly speaking, transport pathway must be inferred based upon geological or geographic constraints. For example, in the context of eolian transport of eroded continental material, truly detrital aluminosilicate grains must be transported by wind to reach the deepest and most distal north Pacific (Rea and Leinen 1988; Kyte et al. 1993; Rea 1994).
For volcanic ash, however, the situation is more complicated. Subaqueous eruptions can lead to significant volcanic input (e.g., Fiske et al. 2001; Maicher and White 2001; White et al. 2003; Tani et al. 2008). Fiske et al. (2001, their p. 822) in particular note how the finest-grained fraction is missing from caldera deposits in the Izu-Bonin system. This “missing material” undoubtedly ends up as dispersed ash throughout the bulk sediment and due to its grain size has the potential to be advected great distances away from its point of origin. Determining this material’s composition in the bulk sediment, a priori will not differentiate between subaerial (eolian) or subaqueous transport.
Subaqueous eruptions can also lead to pumice rafts, which may persist in the ocean for weeks, months, or years (Simkin and Fiske 1983; Risso et al. 2002; Bryan et al. 2004). Even in today’s modern era of enhanced ocean and atmospheric observation, such occurrences are surprises (BBC News, 10 Aug. 2012). Yet, although these events may be uncommon on the human timescale, they are most likely significant pathways of ash to the deep sea over longer time frames.
Mixes of mixtures
In the broad context of geologic material, all non-biogenic rocks and sediments on the surface of Earth can be chemically described as falling along a mixing line or mixing curve between families of primordial materials (e.g., basalts) and families of fractionated “upper continental crust”. Deviations from such a mixing line or curve are due to local provenance effects, authigenic/diagenetic resetting, weathering, and other processes, but the overall relationship holds true. While such a compositional range may seem relatively easy to differentiate analytically (e.g., felsic vs. mafic), the cases are rare when there are only two aluminosilicate sources and they are sufficiently compositionally distant from each other along the mixing line or curve. Far more common is the challenge of resolving multiple sources that are each at different fractional lengths along a theoretical mixing line or curve. For example, continental crust has been approximated as “granodiorite”, “dacite”, or other intermediate composition igneous/volcanic rocks (e.g., Taylor and McLennan 1985), and therefore distinguishing eroded continental crust from wind-blown dacitic ash is challenging. Or, still more challenging are scenarios whereby two disparate sources such as a marine basalt and a wind-blown dust of broad continental crust composition are both authigenically altered to, for example, assorted smectites, and thus have the potential to appear as a single source.
The above examples speak to the importance for geochemical studies of dispersed ash to address their attention to refractory elements that are appropriate to unravel mixing problems and that will also be relatively unaffected by diagenetic and authigenic processes. There are no chemical elements that unambiguously record any single geochemical provenance or domain. Within the spectrum of potential elements for use in general characterization as well as the multivariate statistics discussed below, inclusion of certain common major elements such as Al, Ti, and Fe, along with certain common trace elements such as La and Sc, proves to be beneficial. On a case-by-case basis, certain other key elements such as Th, Nb, and Cr can be advantageous as well (e.g., Plank 2005), although interpretations based on only a few elements are likely to be less representative than studies based on suites of many elements. However, common elements involved in reverse weathering reactions (e.g., Mg, Mackenzie and Garrels 1966; Presti and Michalopoulos 2008) should be avoided for such studies of provenance, given their labile behavior.
The contribution from geochemistry teamed with multivariate statistics
A variety of geochemical approaches can help resolve such mixing issues. In certain situations, such as in the Caribbean Sea example below, single element “normative calculations” (e.g., Leinen 1987) are sufficient, while in other cases multiple different analytical and/or computational approaches need to be simultaneously deployed to develop a more holistic understanding of the geochemical variability within datasets. We emphasize here a combined geochemical approach that generates a wide-ranging elemental suite that is examined with multivariate statistics.
The overall approach we summarize in this paper is based on Q-Mode Factor Analysis (QFA) and two forms of multiple linear regression, a Constrained Least Squares (CLS) technique and a Total Inversion (TI) technique (Pisias et al. 2013). The history of these techniques, as well as the specific MATLAB scripts to apply them to marine sediment chemistry (and recommendations for their use), are detailed in Pisias et al. (2013). The interested reader is also pointed toward previous papers by Dymond (1981), Leinen and Pisias (1984), Zhou and Kyte (1992), and Kyte et al. (1993). In our research group, we have successfully used these techniques in marine sediment from the Cariaco Basin, Arctic Ocean, equatorial Pacific, northwest Pacific Ocean, and South Pacific Gyre (Martinez et al. 2007, 2009, 2010; Ziegler and Murray 2007; Ziegler et al. 2007, 2008; Scudder et al. 2009, 2014; Dunlea et al. 2015a, b), demonstrating their utility throughout a variety of oceanic depositional regimes.
QFA is a terrific tool because—among other things—it is an “objective” technique (e.g., Leinen and Pisias 1984) that is minimally affected by inadvertent researcher bias. There are no inputs other than the data itself. It is limited, however, in many cases in that the resultant compositional factor scores may not be geologically reasonable or geologically precise enough across the spectrum of the wide element menus commonly generated in today’s world of rapid geochemical analysis. Factor analysis is best used to help identify the number of independent components (also referred to as “end members”) and their general composition, but not necessarily the extremely specific composition thereof. Therefore, one of the limitations of using QFA alone is that the user often cannot identify the specific geologic source(s) of the bulk sediment.
The number of end members necessary to best describe the variability of the dataset (that is, the number of factors indicated by the QFA) helps steer the CLS and TI multiple linear regressions. Specifically, in order to identify the exact sources identified by QFA, the CLS or TI linear regressions must be applied. In CLS and TI, the researcher inputs the composition of potential end members and mixes them until the best solution is reached (the differences between CLS and TI are detailed in Pisias et al. (2013)). Thus, we use the QFA to generate an objective “answer” as to the number of sources and their broad composition(s), and then the CLS and/or TI, based on thoughtful selection of potential sources derived from knowledge of previous work and the local/regional geology, to generate the quantitative mix of specific sources. Libraries of potential end members are typically (a) constructed from the literature of all likely volcanic contributors (that is, individual papers about the geochemistry of particular volcano or region), (b) compiled from international global databases (e.g., EarthChem; http://earthchem.org), and/or (c) developed internally from the study’s own data (e.g., using the composition of a discrete ash layer to assess whether it could potentially be a contributor to the dispersed ash component.).
Despite the quantitative attractiveness of applying statistical treatments to a well-measured geochemical dataset, there is no single diagnostic “magic bullet” to fulfill the task of identifying the dispersed ash component within bulk sediment. Instead, a series of interpretative techniques must be used prior to applying the statistical techniques. The use of standard geochemical approaches such as expressing data as concentrations, calculation of fluxes and/or elemental ratios, study of simple coefficient of determination (R 2) matrices, x-y diagrams, and other well-established approaches is extremely important. Such approaches define the boundaries for mass balance, allow comparison with lithologic descriptions and mineralogy, help ground the ensuing statistical treatments, and, in a way that is hard to quantify, ensure that the researcher is intimately familiar with the fundamental underpinnings of each dataset.
Finally, statistical treatments such as those discussed here often lead to non-unique solutions. Contextual oceanographic or geological knowledge plays a major role, however, and can eliminate some of the non-unique solutions. Our group takes a very labor-intensive approach to dealing with this broad subject for both factor analysis and multiple linear regression, strategically built around performing dozens to hundreds of statistical runs per dataset to assess sensitivity of, and variability in, the results (Scudder et al. 2009, 2014; Dunlea et al. 2015a,b). Each dataset is different, and we have found some in which any variation in one element will make a difference; but in another dataset varying a different element will exert a larger lever arm. We take great care to ensure that our results are not dependent upon, or unique to, one or two narrow statistical models nor to one or two specific elements. Doing so would be counter to the very nature of our task at hand—to develop a widely applicable, internally consistent understanding of “What is marine sediment made of?”
In this section, we present a review of previously published studies focused on unraveling bulk marine sedimentary compositions. These case studies range from a simple three-component system (Caribbean Sea) in which element normative calculations alone are sufficient to determine the end members, to a very complex system in which the bulk sediment is composed entirely of aluminosilicates with very similar compositions that requires a combination of geochemical and statistical technique in order to identify the individual compositions (Izu-Bonin-Mariana Arc).
Caribbean sea: a simple case
The Caribbean Sea is ringed by volcanic arcs (Fig. 1; Sigurdsson 1999). To the west rises the Central American volcanic arc system, with a spectrum of volcanic edifices ranging in size from basaltic cinder cones to large stratovolcanos and calderas. To the east is the Antilles island arc, from which some of the most famous volcanic eruptions in the world originate (e.g., Lesser Antilles, Carey and Sigurdsson 1978). These combined volcanic systems contribute large amounts of ash to sediment in the Atlantic Ocean and Caribbean Sea from the Miocene on (Carey and Sigurdsson 1980, 2000; Peters et al. 2000; Jordan et al. 2006; Expedition 340 Scientists 2012; Le Friant et al. 2013) Ocean Drilling Program (ODP) Leg 165 cored throughout the Caribbean Sea (Fig. 1) with its most important objectives being related to the Cretaceous-Neogene bolide impact. One surprise that resulted from this research cruise was the startling number of discrete ash layers (Fig. 3, Carey and Sigurdsson 2000; Sigurdsson et al. 2000), their extent in time and space of which was unexpected. In addition to the discrete ash layers, shipboard study observed ash dispersed throughout the background sediment. Bulk chemical analyses of the bulk sediment allowed for the development of a single-element normative calculation scheme to quantify the abundance of this dispersed ash in these carbonate-rich sediments (Peters et al. 2000). Fortuitously, most of the sequence is a relatively simple three-component system (of CaCO3, terrigenous, and ash), which facilitated the study of dispersed ash in parallel to the discrete layers. Petrographically, the bulk sediment appeared to consist of only carbonate and aluminosilicate clay—and the aluminosilicate clay was assumed to be entirely comprised of eroded terrigenous material (Peters et al. 2000).
Bulk chemical analyses, however, demonstrated that the sediment was vastly depleted in Cr beyond that, which could be explained by carbonate dilution. For example, in a sample with an equal (50 and 50 %) mix of CaCO3 and terrigenous clay, one would predict there should be ~55 ppm Cr in the bulk composition (based on typical “average shale” of ~110 ppm Cr, using Post-Archean average Australian Shale [PAAS] from Taylor and McLennan (1985) to broadly represent an upper crustal terrigenous source). However, such a sample would instead present <10 ppm Cr, indicating that the brown aluminosilicate groundmass was not solely detrital terrigenous material (Peters et al. 2000).
Given the simple three-component system, normative calculations (Leinen 1987) were appropriate to identify the sources to the bulk sediment. Peters et al. (2000) based their calculations on Cr, given that the end member values of Cr in typical shale (110 ppm) and rhyolite (<3 ppm) are strongly divergent. Thus, in a three-component system of CaCO3 (which is quantified precisely by coulometry), terrigenous material (calculated via Cr), and ash, the amount of ash can be calculated by difference, as follows:
Peters et al. (2000) thus documented on a sample-by-sample basis that dispersed ash comprises 15–20 wt.%, with a maximum of 45 wt.%, of the bulk sediment in the western Caribbean. These values were consistent with the sedimentological smear-slide analyses (Sigurdsson et al. 1997) but were more precise.
Peters et al. (2000) also observed that the timing of the accumulation rate of dispersed ash paralleled the sedimentation rate of the discrete layers, although the maxima in dispersed ash preceded the Miocene and Eocene maxima in discrete layers by ~2–4 Ma (Fig. 4). They interpreted the relative timing as recording arc evolution, with the dispersed ash being generated by smaller volcanoes characteristic of the more juvenile arc, and the larger discrete layers representing a mature arc characterized by larger stratovolcanoes and caldera systems, as suggested by Carey and Sigurdsson (2000) and Sigurdsson et al. (2000). These are capable of injecting large plumes of Central American co-ignimbrite ash into the lower stratosphere and upper troposphere, that is, the ideal atmospheric height to facilitate west-to-east blowing wind transport (e.g., rather than transport from east-to-west in the higher stratosphere) (Fig. 4). This interpretation is consistent with the previous studies that have shown that Paleogene and Neogene Central American volcanism is predominantly characterized by larger ignimbrite-forming eruptions (Jordan et al. 2006) that may have frequently produced co-ignimbrite ash plumes reaching lower stratospheric heights (~15 to 20 km; e.g., Woods and Wohletz 1991; Bursik 2001), in contrast to the higher stratospheric eruption columns of Plinian eruptions (>>20 km; e.g., Kutterolf et al. 2008a).
Equatorial pacific ocean: a complex case
Our group also has a long-standing interest studying the equatorial Pacific (e.g., Murray and Leinen 1993, 1996; Murray et al. 1993, 1995, 2000; Kryc et al. 2003; Ziegler and Murray 2007; Ziegler et al. 2007, 2008, plus others). The non-biogenic component of these sediments includes terrigenous clay and ash, which are challenging to resolve in sediment with more than 98 % biogenic material (carbonate and biogenic silica). Some of our work specifically targeted how to resolve the eolian, ash, and authigenic components of these sediments and built upon the classic research of the long-standing Michigan group and their progeny (e.g., Hovan et al. 1991; Rea 1994; Rea et al. 1998).
For example, Ziegler et al. (2007) detailed chemical criteria that can be applied to differentiate authigenic, terrigenous, and volcanogenic aluminosilicates from each other. Sequential extractions were performed at ODP Site 1215 (Fig. 1) to remove non-aluminosilicate components. The material remaining upon completion of the extraction procedure was termed the “residual” component, consistent with established protocols. La-Sc-Th ternary diagrams and PAAS-normalized rare earth element (REE) patterns (Fig. 5a) and reference REE patterns (Fig. 5b) were used to aid in determination of the sedimentary components. In the residual component, Ziegler et al. (2007) quantified upper continental and lower crustal components using selected rare earth element (REE), Sc, and Th abundances. In old (>50 Ma) nannofossil ooze, the residual component exhibited a large La contribution. Additionally, the residual component of the nannofossil ooze fell outside the boundaries of a simple two component mixing between upper and lower crust components. REE patterns for these samples exhibit sharp, seawater-like negative Ce anomalies, providing a clear indication that an authigenic phase is present in the residual component (Fig. 5c). The old age of these sediments may contribute to the formation of the authigenic phase, given that such samples have likely experienced significant diagenesis. In this way, the geochemical approach clearly identified samples in which it is virtually impossible to differentiate eolian material from volcanic ash (Fig. 5c, d).
Izu-Bonin-Mariana Arc (ODP Site 1149 and DSDP Site 52)
One of the goals of ODP Leg 185 was to test whether subducted sediments control along-strike geochemical differences in Izu-Bonin-Mariana arc composition (Fig. 1, Plank et al. 2000). In addition to the potential influence of the terrigenous (non-ash) sedimentary component, the amount of ash in the sediment column is critical to constrain, not only for the determination of absolute geochemical fluxes into the “Subduction Factory” but also in order to determine how much of the input is “recycled” from the arc itself. Due to the long-standing interest in the region from a variety of geological perspectives, there is also a wealth of tectonic- and arc-related information to draw upon in the context of both ash layers and dispersed ash.
Preliminary work based on a Nb-based normative calculation showed that 33 ± 9 wt.% of the sediment at ODP Site 1149 is comprised of dispersed ash (Plank et al. 2000). As described in Scudder et al. (2009, 2014), in order to determine the sources to the bulk sediment, we followed the QFA and TI approaches and MATLAB scripts from Pisias et al. (2013). The elemental suite we targeted was composed of refractory elements predominantly associated with aluminosilicate components (Al, Ti, Sc, Cr, Ni, Nb, La, Th) as these are the most likely to identify differences between source components. The QFA results indicate that four factors (end members) explain 97 % of the variability of the bulk sediment (Scudder et al. 2014, Fig. 6). Given that QFA alone is not sufficient to identify the source of these factors, TI modeling was employed. The TI modeling identifies a combination of Chinese Loess (CL), rhyolitic ash from the Honshu arc (HR), mafic ash from the Izu-Bonin Front Arc (IBFA), and a second eolian dust (termed “Eolian 2”) that best explain the total chemical composition of the bulk sediment.
Based on the TI results, the dispersed ash mass accumulation rate (MAR, g/cm2/ky) at Site 1149 can be calculated and compared to the MAR of a series of ash layer parameters. At this site, the number of ash layers most closely tracks the total dispersed MAR (that is the sum of HR + IBFA). That the number of layers is most similar to the dispersed MAR suggests that eruption frequency, rather than eruption size, is the driving mechanism for the dispersed ash record (Scudder et al. 2014, Fig. 7).
The MAR patterns of the ash components are consistent with published eruption records of both the Izu-Bonin and Honshu arcs, and we can interpret these changes in accumulation rate in terms of arc history (Fig. 8). Focusing first on the Honshu Rhyolite, we observe that this component is the dominant dispersed ash, even though the Honshu arc is relatively far away. Given Site 1149’s distal location, eruptions from the Honshu arc could have been large and yet resulted in only thin layers. These layers may subsequently be mixed into the bulk sediment to create the dispersed ash component. Alternately, the dispersed ash could simply represent an increase in deposition of ash from the atmosphere. The MAR of HR is consistent with the tectonic history of the Honshu arc, particularly through the younger portions of the record (e.g., Taira 2001). For the IBFA component, the models closely track the temporal changes in the tectonic record of Izu-Bonin (e.g., Sibuet et al. 1987). MAR patterns indicate that a gradual increase in IBFA volcanism occurred from ~18–10 Ma, with a burst of activity from ~4.5–3 Ma followed by a steady increase beginning at ~2 Ma (Scudder et al. 2014, Fig. 8).
We can compare and contrast Site 1149 to DSDP Site 52 in the northern Marianas arc (Fig. 1). Site 52 contains extremely high abundances of volcanic ash not directly linked to a specific eruption style (upwards of 50 % volcanic glass mixed in the brown clay; Fischer et al. 1971). Unfortunately, rotary drilling at Site 52 left only a few ash layers intact (all in the upper 20 mbsf; Fischer et al. 1971). Applying QFA with the same chemical suite as used at Site 1149 indicates that four factors (end members) are present (Fig. 6). Two of these factors closely resemble those found at Site 1149, while the other two do not correspond well, if at all (Scudder et al. 2014). Given the limitations of QFA described previously, this interpretation is based on the factor scores (the weight of each element on the discrimination of a single factor) and the broad compositional scores produced by the modeling. TI linear modeling confirms this interpretation, identifying a mix of Chinese Loess, IBFA, dispersed boninite from the Izu-Bonin arc (BNN), and a dispersed felsic ash with the same composition as felsic layers from Site 52 (referred to as Felsic52) as best explaining the bulk sediment chemical composition.
Site 52 presents some key similarities and differences from Site 1149. First, the total amount of dispersed ash (regardless of composition) at both sites is very high, averaging 30 ± 17 wt.% at Site 1149 and 36 ± 18 wt.% at Site 52. Second, whereas at Site 1149 the two ash sources (HR, IBFA) are found both as layers and as dispersed ash, at Site 52 at least three volcanic sources are required to explain the bulk composition of the sediment. The discrete layers appear to be IBFA and felsic ash layers from Site 52, while the dispersed ash is comprised of IBFA, Felsic52, and an additional component, average Izu-Bonin Boninite (BNN). Therefore, at Site 52, the ash layers and the dispersed ash are partially compositionally decoupled from each other (Scudder et al. 2014).
In this section, we present new data and ongoing observations from a variety of settings in the Northwest Pacific. While some of this research may still be developing, we include it here in order to show the strength of the combined geochemical/statistical technique in moving toward a regional perspective of inputs to the Western Pacific.
Nankai Trough, IODP Sites C0011 and C0012
IODP Sites C0011 and C0012 (Fig. 1), drilled as part of the Integrated Ocean Drilling Program (IODP) NanTroSEIZE transect, are located in the Shikoku Basin ~100 km southeast of the Kii Peninsula and ~160 km west of the Izu-Bonin arc on the Kashinosaki Knoll, a prominent bathymetric high. Located near the crest of the Kashinosaki Knoll, Site C0012 represents a condensed sediment section in comparison to Site C0011, which is located on the northwestern flank. The main goal of NanTroSEIZE is to drill across the up-dip limit of the seismogenic and tsunamigenic zone over the Nankai Trough subduction boundary, along which mega-thrust earthquakes are known to occur (Tobin and Kinoshita 2006). Shipboard sedimentological smear slide analyses at both Sites C0011 and C0012 estimate that on average dispersed ash constitutes ~25–30 wt.% through Units I and II, and decreases to ~7–15 wt.% in the hemipelagic facies of Unit III (Saito et al. 2010; Henry et al. 2012).
Statistical analyses of newly acquired data from Sites C0011 and C0012 were performed using the same element suite as that applied to Site 1149. At Site C0011, QFA indicates that three factors explain 99 % of the variability of the bulk sediment (Fig. 9). While we cannot determine the exact composition of the end members from QFA, one of the modeled sources appears to be intermediate (roughly equal contributions of most of the elements in the model, that is, of Sc, Cr, Ni, Nb, La, and Th) in composition while the other two are broadly felsic (contributions driven by Al, Ti, and Sc, with lesser covarying Nb, La, and Th). CLS multiple linear regression analysis suggest that the three sources at Site C0011 are consistent with one being PAAS, and the other two being ashes having compositions similar to a representative Rhyo-Dacite and Rhyolite from the Honshu Arc (HR) (Fig. 10). These latter two sources may in fact be dispersed ash but could also be ash that has since been altered and yet retained its refractory chemical signature. Regardless, these two types of dispersed ash and/or clay minerals with comparable geochemical signatures comprise 36 ± 8 wt.% of the bulk sediment. Evidence for multiple sources of volcanic material, and/or the chemically equivalent clay-alteration products, is consistent with studies of tuffaceous and volcaniclastic sandstones from this site, which calls for volcanic material from both the Izu-Bonin and Honshu Arcs (e.g., Pickering et al. 2013; Schindlbeck et al. 2013; Kutterolf et al. 2014).
Applying the same methods to Site C0012, QFA indicates that four factors (end members) explain 99 % of the variability in the bulk sediment (Fig. 9). The modeled compositions of the bulk sediment at Site C0012 identify two intermediate and two felsic end members for the geochemical proxies. CLS indicates that these end members are best explained by mixing PAAS and three ashes: the dacitic ash layers from Site C0012, rhyolite from the Izu-Bonin Arc (IBR), and andesite from the Izu-Bonin Arc (IBA). Collectively, the ash compositions (and/or their chemically equivalent clay-mineral alteration products) contribute approximately one-half (49 ± 10 wt.%) of the bulk sediment (Fig. 10). Here, it is important to recall that our geochemical approach cannot resolve the pathway by which the ashes have reached these sites, as some of these ashes may be eroded from terrestrial deposits in the Japanese archipelago.
We compare the mass accumulation rate of the dispersed ash (or its clay alteration) component to a number of common ash layer parameters, including the number of ash layers per 0.2 Ma, the thickest ash layer per 0.2 Ma, and the total thickness of ash layers per 0.2 Ma. We binned the data by 0.2 Ma units, in order to generate a discrete ash layer dataset of approximately the same temporal resolution as that of our dispersed ash record (Fig. 11).
When compared to various ash layer parameters, we find that the MAR of the total dispersed ash component at Site C0011 correlates best with “Thickest Layer” in Unit I. This suggests that through this interval, eruption volume, rather than the frequency of explosive eruptions, drives the dispersed ash accumulation (Fig. 11). In contrast, in Unit I of Site C0012, the number of discrete ash layers rather than “thickness” is best correlated to the dispersed ash MAR. At both sites, the number and thickness of ash layers vastly decreases below the Unit I/II boundary while the dispersed ash component remains high as a geochemical proxy. This is reflective of time periods when the volcanism in SW Japan was reduced or eliminated (Mahony et al. 2011), when the sites were influenced by siliciclastic turbidites (Units II, IV, and V), or when dispersal paths from the main detrital sources were further away from eruptive fronts (Unit III). Changes in any of these factors may have resulted in either fewer and/or thinner layers that would be more susceptible to being homogenized (by bioturbation or otherwise). That the geochemical signature equivalent to dispersed ash is high at times when so few ash layers were deposited clearly demonstrates that clay minerals derived from volcanic ash and volcanic rock (e.g., smectite group) are a much greater contributor to the sedimentary sequence than is recorded only by the ash layers.
Shikoku Basin, DSDP Site 444
DSDP Site 444 was drilled during Leg 58 to test hypotheses about the origin of marginal basins (Fig. 1, deVries Klein and Kobayashi 1980; deVries Klein et al. 1980). In particular, the Shikoku Basin portion of Leg 58 was drilled in order to answer questions regarding the basin formation by evaluating various spreading models, the ages of the oceanic crust, sediment evolution, and the paleoceanographic origin of the region (deVries and Kobayashi 1980). Site 444 was selected for our research on dispersed ash because of its abundant volcanic ash layers (for example, in comparison to Sites 442 and 443).
Site 444 contains basaltic, andesitic, and rhyolitic ash (deVries and Kobayashi 1980; Furuta and Arai 1980; and our own studies). Most tephra in other northwestern Pacific DSDP holes are rhyolitic and andesitic, which makes the basaltic nature of the Site 444 tephra geologically and tectonically unusual (White et al. 1980). In the Pleistocene and Pliocene, the ash layers are non-alkali rhyolites. As felsic ash is believed to mainly be a product of explosive volcanic eruptions, these layers could have originated from relatively large-scale eruptions in an island arc setting, most likely located westward of Site 444 and transported in the prevailing westerlies. This direction of transport is evident as grain size increases toward the west and decreases toward the east (Furuta and Arai 1980).
In the Miocene, the tephra is of non-alkali tholeiitic basaltic as well as alkali basaltic composition. These basaltic layers imply that another volcanic source was involved in the Miocene. This source could have been closer to the drilling sites than those sources of rhyolitic and andesitic tephra (possibly the Kinan Seamounts and the Shichito-Iwo Jima volcanic arc), but it could also be the distal evidence for large mafic eruptions from a more oceanic arc source. The knowledge that the occurrence of such large mafic plinian eruptions with a wide dispersion is not limited to arc settings alone and can also be found at ocean island settings (e.g., the Galápagos archipelago, Schindlbeck et al. 2015). Such observations are especially important for future studies of dispersed mafic ash in marine sediments. We note, however, that at least some of these ashes may also be subaqueous in origin. For example, certain volcanic arcs near the Shikoku basin (e.g., Izu-Bonin) contain subaqueous volcanoes (Hochstaedter et al. 2001).
Ash layers were carefully identified throughout the 310 meters of sediment at Site 444 using core photos and the shipboard lithologic description (deVries and Kobayashi 1980). Site 444 was cored using the Rotary Core Barrel (RCB) system, as it was occupied during the early-mid stages of the DSDP prior to the advent of the advanced piston corer. Because of the RCB drilling, the recovered core is highly disturbed. Therefore, we classified the ash deposits as either an “ash layer” or an “ash pocket”. Anything that is ash in distinct form but that is not in the shape of a full horizontal layer (e.g., touching both sides of the core liner) is termed an “ash pocket”. The pockets are often, though not always, circular in form. Ash layers and ash pockets correlate with each other with depth. Thus, we interpret that the pockets are likely to have originated from ash layers mixed by RCB drilling.
A total of 128 ash layers and 76 ash pockets were identified. Of the 28 ash layers chemically analyzed in this study, four (4) of them are categorized as ash pockets. This is important to note when assessing their compositions as any seemingly unusual compositions can be evaluated for mixing with non-ash sources (e.g., clays). The distribution of ash layers and pockets were parameterized by (1) thickness with depth, (2) number of layers per 10 meters, (3) thickest layer (cm) over successive 10 meter depth increments, and (4) total thickness of ash (cm) in that same 10 meter window (Fig. 12). These parameters collectively should yield a baseline understanding of the distribution of ash layers, and we acknowledge that any one of these parameters is not necessarily preferable to the others. Additionally, we note that there is a relatively thick 31-centimeter-thick ash layer at a depth of 30 mbsf (~0.66 Ma, Pleistocene), which may overly influence some of these parameters over that interval.
Ash layers were analyzed for major element glass shard compositions by electron microprobe (average of 15 single shard measurements), and additionally, the bulk ash layers were analyzed by ICP-ES and ICP-MS for major, trace, and REE compositions following the methods of Scudder et al. (2014). Even though the bulk ash data may be compromised by the inclusion of the terrigenous aluminosilicate material (e.g., adjacent pelagic clay mixed into the ash layer or ash pocket; Scudder et al. 2014), we can still infer other key aspects of the distribution of the ash layer/pocket chemistry.
The distribution of key major elements used to differentiate compositional variation, such as SiO2 or TiO2, (Fig. 13), suggests the presence of multiple ash populations ranging from mafic to intermediate to felsic in composition. A transition in ash layer composition is observed at ~160–170 mbsf in which the SiO2 concentration of the bulk ash layers decreases with depth, while the TiO2 concentration of the bulk ash layers increases with depth. At ~160–170 mbsf, the ash layers are enriched in elements such as Sc and V, and these elemental changes are indicative of a shift to ash of intermediate to mafic composition at this depth (Fig. 13). Ternary diagrams (Fig. 14) indicate at least two populations of ash spanning a mixing line between relatively more felsic (dacites and rhyolite sources) and more mafic (basalt sources) end members.
Other existing data supports the hypothesis of multiple ash populations. Some of the Site 444 cores possess visually black and chemically basaltic ash, which is a unique aspect for the Shikoku Basin. Refractive indices of volcanic glass and associated minerals have been documented as an effective means for correlating widespread tephra layers (Machida and Arai 1983). Based on the refractive indices of glass shards from ash layers at Site 444, Furuta and Arai (1980) (their Figure 12) show a linear relationship between refractive index and FeO content. They find that the refractivity of the transition-metal oxides (e.g., FeO, TiO2, and MnO) at this site is higher than that of SiO2 and other oxides, thus the refractive index seems to be driven primarily by the transition-metal oxides. The predominate transition-metal oxides in volcanic glass shards are iron-based (i.e., FeO or Fe2O3), thus at Site 444 the refractive index of volcanic glass shards can be determined by the content of the iron oxides and indicate that basaltic ashes are present. At Site 444, the ash layers are divided into several groups based on petrographic characteristics, chemical composition, and age. As discussed above, Furuta and Arai (1980) identify rhyolitic and basaltic ash layers at Site 444. Multiple ash populations are also apparent in our microprobe and bulk ash layer chemistry.
Downcore profiles of the bulk sediment do not necessarily provide clear distinction of a single source or two-component mixing (Fig. 13). Additionally, ternary diagrams show that the bulk sediment does not necessarily lie along a mixing line (Fig. 14) with an upper continental component (e.g., Chinese Loess or PAAS) influencing the sediment in addition to the ash components discussed above. Thus, there is likely at least one additional end member beyond the multiple ash populations that influences the bulk sediment composition. This will be explored further in our future studies.
Based on the above discussion of compositional trends, QFA was performed on the data at Site 444 using a modified element suite compared to that used for Site 1149 and Site 52 (Table 1). When performing factor analysis, there is a balance that must be maintained between the number of elements and the number of samples in the dataset. Reimann et al. (2002) outline a number of parameters by which to define the appropriate number of elements. We maintain a very conservative use of these rules, and as such during our study of Site 444, with 71 samples in the dataset, we restricted our element menu to seven (7) elements. Of the refractory elements chosen as representative of the aluminosilicate end members (Al, Ti, Sc, Cr, Ni, Nb, La, Th), Ni overall shows the least variability between potential sources and thus was removed from the element menu for our statistical analysis of Site 444.
The results of QFA at Site 444 indicate that three factors (end members) explain 98 % of the variability of the data. This is consistent with the geochemical trends we observe in the bulk data, and the three factors explain 53, 33, and 11 % of the variability of the data respectively (Fig. 15, left). Based on the preliminary modeled compositions of these factors, we interpret that there may be one intermediate crustal source, and at least one dacitic source exhibiting higher Ti/Al ratios, although we cannot differentiate further based on QFA alone. If we were to increase the number of factors, we find that four factors can explain 99 % of the variability of the data, with the four factors explaining 55, 34, 9, and 1 % of the variability of the data, respectively (Fig. 15, right). While this fourth factor is small, we find that it predominantly splits the third factor from the previous QFA and identifies an end member that is dominated by variation in Nb.
In terms of the relative downhole distributions of square factor loadings (Fig. 16), Factor 1 dominates over the upper ~150 mbsf and exhibits a broad decrease in importance with depth. Factor 2 is most important in the sequence below ~150 mbsf. Factors 2 and 3 have roughly equal relative contributions over the upper ~50 mbsf, below which Factor 2 exhibits a broad increase while Factor 3 generally decreases. Future statistical analysis by CLS will allow us to determine whether three or four factors are ultimately the appropriate number of end members and will allow us to further determine the sources to the sediment.
Kamchatka and the Kuriles, DSDP Site 579 and Site 581
DSDP Sites 579 and 581 (Fig. 1) were occupied in June 1982 as part of DSDP Leg 86 and were cored as part of a transect across the Kuroshio Current system designed to investigate the paleoceanography of the northwest Pacific. Although spaced relatively far apart, Sites 579 and 581 comprise an excellent composite section of the region (Plank and Langmuir 1998). Site 579 marks the southern margin of the transition between the sediments of the calcareous-siliceous subtropical gyre and the more siliceous subarctic gyre. It was selected for Leg 86 with the goal of compiling a paleoceanographic record of this transition zone for the late Neogene and Quaternary and comparing this record of migrations of the subarctic front with that of Asian eolian inputs. Site 581 is the northernmost of the transect sites drilled during Leg 86 and was designed to provide a high-resolution record of the late Neogene.
As with the other sites in this region, a number of ash layer parameters were examined (Fig. 12). There are no clear trends evident in the number of ash layers through the depth of the site. There are two peaks in the number of ash layers per 5 m, with seven ash layers from 40–45 mbsf and four layers from 80–85 mbsf. This peak at 80 mbsf also corresponds to a peak in total ash thickness (44 cm thick), meaning that not only are more layers present at this depth but also that those layers are thicker. This suggests a period of increased large-scale volcanic eruptions during the Pliocene. However, this is difficult to verify as late Pleistocene glaciations are likely to have obscured the terrestrial record of eruptive history in this area (Volynets et al. 1999). Ash pockets show good correlation with the ash layers in frequency, and we interpret that they originated from disturbance in the core due to the weather during core recovery. The cores had a high occurrence of “flow-in” zones due to heavy seas that may have affected coring and disturbed recovery of some ash layers (Heath et al. 1985).
Interpretation of the bulk ash layers and bulk sediment downhole is not straightforward (Fig. 13). In ternary diagrams, the bulk sediment commonly falls along a mixing line that can be explained by the bulk ash and a relatively more basaltic component, supporting the presence of dispersed ash in the sediment (Fig. 14). Much of the bulk sediment is similar in composition to Chinese Loess, which, while not necessary to explain the composition of the bulk sediment, can be inferred to be almost surely present due to the location of the sites.
Applying QFA to the combined data from these sites, we find that either five or six factors best explain the variability of the data (Table 2, Fig. 17). Comparison of the two sets of factor analysis indicates that Factors 1 through 4 correlate with each other whether there are five or, alternatively, six factors. If there are six factors, Factor 5 from the smaller factor model is split between Factors 5 and 6. Factor 6 explains 1.7 % of the variability of the data in this model, and thus it is interpreted as “real”.
Focusing first on the five-factor model, the calculated compositions of the end members identifies Factor 4 (explaining 10.1 % of the variability) as a potential terrigenous source. This is unusual, as in all the other NW pacific sites discussed in this paper the crustal source is the first and/or second end member explaining the majority of the variability in the dataset. This speaks to the importance of dispersed ash at Site 579/581, since the dispersed ash component(s) appear to be controlling most of the variability. This will be further explored in future work. The six-factor model identifies a few factors that are dominated by a single element (Al in Factor 4, Ti in Factor 5) indicating that the division of factors is controlling variability as opposed to their specific concentrations.
As with Site 444, square factor loadings for these Kamchatka/Kurile sites can allow us to assess the relative contribution of the individual factors on a sample-by-sample basis (Fig. 18). In order to assess the relative contributions for this work, we will focus here on the five-factor model. We observe that for most of the sedimentary record, Factor 1 dominates the record, although from ~65 to ~93 mbsf, Factor 2 is the dominate component. Additionally, from ~150 to ~240 mbsf the variance in the record is dominated by Factor 3 (~150 to ~200 mbsf) or Factor 2 (~200 to ~240 mbsf). Factors 4 and 5 are remarkably similar in importance until ~200 mbsf below which Factor 4 increases in relative importance while Factor 5 remains fairly stable. Future statistical analysis by CLS will allow us to determine whether five or six factors are ultimately the appropriate number of end members and will allow us to further determine the sources to the sediment.
Although the presence of dispersed ash in marine sediment has been long known by marine sedimentologists, the overall quantification of its abundance and its composition has recently received renewed attention. The dispersed ash, either altered or unaltered, is extremely difficult to differentiate from detrital/terrigenous/authigenic clay as they are all, fundamentally speaking, “aluminosilicates”. The combined geochemical (major, trace, REEs) and statistical (Pisias et al. 2013) approach provides the chemical context for the determination of provenance and the distinctive resolution of the different aluminosilicate components based on their individual geochemical signature(s).
The case studies we present here show that this approach can be useful in multiple different arc systems. We have also shown that by adding the dispersed ash component to the study of discrete ash layers, many additional geological and oceanographic interpretations can be uncovered. Most obviously, we have shown how geochemical modeling of the bulk sediment composition can indicate the presence of an additional ash source that is not recorded in the discrete layer record. Furthermore, in cores where there are no remaining discrete layers (either due to natural bioturbation or man-made coring disturbance), we show that important ash contributions may still be recognized and studied for their composition and accumulation. We have also shown how the accumulation of dispersed ash will either best correlate with the thickest ash layer, or alternatively, the frequency of the discrete ash layers, which lead to dramatically different interpretations regarding the volcanic mechanisms of a given arc. Finally, when considering these studies throughout the northwest Pacific Ocean, or in marginal basins such as the Japan Sea, our approach may be used to develop a mass balance inventory of the total mass of volcanic ash that is more accurate than estimates based solely on the combined thicknesses of the discrete layers.
There are many other future research directions that are a natural extension of the work described above. There are a number of regions for which the characterization of the abundance and extent of dispersed ash would be of great scientific and societal importance (e.g., Tonga, Costa Rica, and Indonesia), and studying the dispersed ash component in these regions will most certainly lead to an improved understanding of explosive volcanism in those systems. Moreover, most marine volcanoes are beneath the sea surface, either in mid-ocean ridge settings or in convergent margins (e.g., Fiske et al. 2001; White et al. 2003). The vast majority of these eruptions go unobserved and their products are often unrecovered and thus are understudied. Often the only evidence of subaqueous eruptions are widespread pumice rafts. Little is known, however, about the fate of these rafts, yet they too are likely to contribute dispersed ash to the sediment.
Volcanic ash may have significant nutrient fertilization potential as well. Particulate matter from large volcanic eruptions may release enough iron and other nutrients to the surface ocean to stimulate primary production over short time scales (Watson 1997; Olgun et al. 2011). Thus, it would be important to develop an understanding of the effects of iron and other elements from volcanic ash on the biological productivity of the open ocean and, second, to consider the biological effects of volcanic ash-driven elemental fertilization in the open ocean through Earth’s history. The use of the dispersed ash record can be applied to achieve these goals.
Additionally, ash, with its major component being volcanic glass, is a metastable phase with high potential biological availability to the subseafloor ecosystem, may provide both electron donors and electron acceptors important to microbial energetics. Characterizing the chemistry of the subseafloor sediment will provide vital information about the nutrients available to subseafloor microbial life as well as the pathways by which these nutrients are utilized.
Constrained Least Squares
- CRISP II:
Costa Rica Seismogenesis Project Stage II
Deep Sea Drilling Project
Izu-Bonin Front Arc
Inductively Coupled Plasma-Emission Spectrometer
Inductively Coupled Plasma-Mass Spectrometer
Integrated Ocean Drilling Program
lower red clay MAR, mass accumulation rate
Mid-Ocean Ridge Basalt
Ocean Drilling Program
Post-Archean average Australian Shale
pale green laminae
Q-Mode Factor Analysis
Rotary Core Barrel
rare earth element
upper red clay
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This research used samples and/or data provided by the IODP. RPS and RWM thank the US Science Support Program (USSSP) of IODP, NSF OCE-0136855, and NSF OCE-0958002 for financial support, and T. Ireland, A. G. Dunlea, N. Murphy, and J. W. Sparks for laboratory assistance. JCS and SK thank the German Research Foundation for financial support (KU-2685/1-1, 2-1&2) and M. Thöner, K. Strehlow for laboratory assistance. Portions of this material are based upon work supported while RWM was serving at the National Science Foundation. Thanks to those who reviewed and commented on the manuscript.
The authors’ declare that they have no competing interests.
RPS is the lead author of the paper, performed the ICP-ES and ICP-MS analyses, and led the research and multiple conversations/interactions with the research team. RWM funded the research (see Acknowledgements), performed the oversight of the project, advised then-Ph.D. student RPS and then-undergraduate students SG, RL, and CCM, facilitated the discussion with co-authors and community, and contributed the text. JCS and SK performed microprobe analyses of volcanic glass from ash layers, discussed the research, contributed revisions of the text, compiled the reference list, created Figs. 1, 2, and 4, and provided the interpretation of the data. SK funded the research (see Acknowledgements) and advised Ph.D. student JCS regarding ash chemistry. FH reviewed and revised the manuscript. MBU discussed the research, contributed the revisions of the text, and provided the interpretation of the data. SG, RL, and CCM assisted in the ICP-ES and ICP-MS analyses, were involved in the preliminary statistics and interpretations of Sites 52, 444, and 579/581, and reviewed and commented on the manuscript. All authors read and approved the final manuscript.