Progress in Earth and Planetary Science

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Review
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Mantle hydration and Cl-rich fluids in the subduction forearc

Progress in Earth and Planetary Science20163:9

DOI: 10.1186/s40645-016-0090-9

©  Reynard. 2016

Received: 14 December 2015

Accepted: 19 April 2016

Published: 28 April 2016

Abstract

In the forearc region, aqueous fluids are released from the subducting slab at a rate depending on its thermal state. Escaping fluids tend to rise vertically unless they meet permeability barriers such as the deformed plate interface or the Moho of the overriding plate. Channeling of fluids along the plate interface and Moho may result in fluid overpressure in the oceanic crust, precipitation of quartz from fluids, and low Poisson ratio areas associated with tremors. Above the subducting plate, the forearc mantle wedge is the place of intense reactions between dehydration fluids from the subducting slab and ultramafic rocks leading to extensive serpentinization. The plate interface is mechanically decoupled, most likely in relation to serpentinization, thereby isolating the forearc mantle wedge from convection as a cold, potentially serpentinized and buoyant, body. Geophysical studies are unique probes to the interactions between fluids and rocks in the forearc mantle, and experimental constrains on rock properties allow inferring fluid migration and fluid-rock reactions from geophysical data. Seismic velocities reveal a high degree of serpentinization of the forearc mantle in hot subduction zones, and little serpentinization in the coldest subduction zones because the warmer the subduction zone, the higher the amount of water released by dehydration of hydrothermally altered oceanic lithosphere. Interpretation of seismic data from petrophysical constrain is limited by complex effects due to anisotropy that needs to be assessed both in the analysis and interpretation of seismic data. Electrical conductivity increases with increasing fluid content and temperature of the subduction. However, the forearc mantle of Northern Cascadia, the hottest subduction zone where extensive serpentinization was first demonstrated, shows only modest electrical conductivity. Electrical conductivity may vary not only with the thermal state of the subduction zone, but also with time for a given thermal state through variations of fluid salinity. High-Cl fluids produced by serpentinization can mix with the source rocks of the volcanic arc and explain geochemical signatures of primitive magma inclusions. Signature of deep high-Cl fluids was also identified in forearc hot springs. These observations suggest the existence of fluid circulations between the forearc mantle and the hot spring hydrothermal system or the volcanic arc. Such circulations are also evidenced by recent magnetotelluric profiles.

Keywords

Subduction Fluids Forearc mantle Salinity Chlorine

Review

Introduction

The forearc region of subduction zones is a location of intense aqueous fluid circulations that influences major geologic phenomena. At shallow (~0–30 km) depth, the seismic cycle on the plate interface, with events ranging in timescale from regular earthquakes to slow earthquakes and post-seismic relaxation, is thought to depend on the building and release of fluid pressure on fault planes fed by compaction and dehydration reactions in the subducting slab (Peacock and Wang 1999; Sleep and Blanpied 1992). Above the plate interface, such fluids interact with rocks ranging from sediments of the accretion wedge to mantle in the deepest part of the forearc region. In the shallowest part, fluids can be directly sampled at seepage, hydrothermal vent, and in mud volcanoes. They document interactions between different sources of pore water and metamorphic dehydration water from the overriding plate, subducting oceanic crust, and sediments (Kastner, et al. 2014).

At greater depths and down to the source of magmatic liquids, connections between fluids rising to the surface and deep fluid sources are tenuous (Kawamoto, et al. 2013). Mixing of deep fluids (from more than 50 km depths) with meteoritic waters has been evidenced in hot spring. Evidence for fluid and fluid interactions with rocks may be inferred from geophysical properties such as seismic velocities and electrical conductivity, and from petrophysical modeling based on experimental data. At depths near ~20–40 km, non-volcanic tremors (Obara 2002) and other slow events occur near or above the plate interface (Dragert, et al. 2001; Rogers and Dragert 2003; Shelly, et al. 2006). These are associated with portions of the oceanic crust whose seismic properties suggest fluid overpressure (Audet, et al. 2009; Audet and Schwartz 2013). Deeper (>30 and down to 60–90 km depths), the plate interface is decoupled and seismically silent (Wada, et al. 2008), and diffuse seismicity in the oceanic crust is linked to eclogitization reactions (Hacker, et al. 2003; Kita, et al. 2006). The region above the decoupled plate interface is tectonically isolated and its nature can only be probed by geophysical means.

In the deep forearc wedge, water may be stored in the form of hydrous minerals whose presence results in seismic velocity decrease compared with anhydrous lithologies (Abers 2000; Bostock, et al. 2002; Helffrich and Abers 1997). Further decrease in seismic velocity and variations of VP/VS ratio is expected if excess fluid pressure develops at depths (Peacock, et al. 2011; Schubnel, et al. 2006). If fluids are connected, this will also result in variations of electrical conductivity that can be mapped by magnetotelluric surveys in subduction zones (Baba, et al. 2010; Wannamaker, et al. 2014).

Serpentine and serpentinites are candidates with which to explain the observation of reduced velocities and water storage in the forearc. Geophysical evidence for the presence of hydrated lithologies and fluids at 30–90 km depths corresponding to the deep forearc region of subduction zones will be addressed in light of recent experimental determinations of geophysical properties of serpentines and serpentinites. Interpretations of seismic velocities based on petrophysical models are simple when isotropic rock properties are considered, but become complex when different varieties of serpentine and anisotropy are taken into account. High electrical conductivities require the presence of large salinity variations in aqueous fluids in the forearc mantle. Potential links with geochemical signatures of arc magmas, hot spring fluids of deep origin, and of exhumed serpentinite bodies in high-pressure ophiolites will also be discussed.

Geophysical observables and constrains

Heat flow, rheology, and geodynamical modeling

Seismic activity, heat flow data, and geodynamical modeling (Abers, et al. 2006; Syracuse, et al. 2010; van Keken, et al. 2002; Wada and Wang 2009) are used to constrain the rheological behavior of the subduction interface. Three major segments can be distinguished. Firstly, the shallow seismogenic zone, secondly, an intermediate depth “decoupled” interface is characterized by low friction coefficient or low viscosity, and finally a deep coupled interface where the overlying mantle is entrained with the slab by viscous drag. Depths of the transitions are about 30 km between the seismogenic and decoupled zones (Hyndman and Wang 1993) and 75 ± 15 km between decoupled and coupled zones as constrained from heat flow data (Wada and Wang 2009). The existence of the decoupled interface results in the formation of a static region in the forearc mantle, the so-called cold nose. This region is isolated from convection and is necessary to match the low heat flow values (Abers, et al. 2006; Wada, et al. 2008). Temperatures in the cold nose (Wada and Wang 2009) match the stability of serpentine (Ulmer and Trommsdorff 1995), the dominant hydrated phase in ultramafic compositions. The low viscosity of serpentine inferred experimentally accounts for the mechanical decoupling of the plate interface at these depths (Amiguet, et al. 2012; Chernak and Hirth 2010; Hilairet, et al. 2007; Hirauchi, et al. 2010).

Seismology

Constrains on the structure of the forearc comes mostly from seismic tomographic studies, either arrival time tomography (Hasegawa, et al. 2008; Matsubara, et al. 2009; Nakajima, et al. 2009; Ramachandran and Hyndman 2012) or receiver function analysis (Audet, et al. 2009; Bostock, et al. 2002; Kawakatsu and Watada 2007; Nikulin, et al. 2009). Absolute velocities and velocity contrasts between different structural and lithological bodies are imaged. Another source of information is seismic anisotropy, which is sometimes derived at high resolution using both approaches above, and also with seismic wave splitting measurements (Long and van der Hilst 2006). Seismic velocities and velocity are sensitive to lithology, anisotropy, pressure, temperature, and to free fluid content especially when overpressured.

Seismological data can be compared with laboratory measurements of sound wave velocities of bulk rocks (Christensen 1996; Christensen 2004), or with petrophysical models derived from combination of single-crystal elasticity and crystal-preferred orientations in rocks (Mainprice 1990). In the absence of data on anisotropy, the isotropic approximation is justified if rocks are isotropic, a fact that can be verified only with laboratory measurements or petrophysical calculations, or if velocities are constrained from or seismological studies with randomly oriented seismic rays. Petrophysical models and acoustic measurements along different directions give access to anisotropy. Seismic velocities obtained from petrophysical modeling (Bascou, et al. 2001; Bezacier, et al. 2010a; Bezacier, et al. 2010b; Cao, et al. 2013) are in good agreement with measurements on rock aggregates (Ji, et al. 2013; Shao, et al. 2014). They provide a basis for estimating the proportion of water stored in minerals.

Typical isotropic VP/VS relationships for subduction zone lithologies encountered show a nearly constant VP/VS ratio of 1.732 (√3 or equivalent Poisson ratio of 0.25) for isotropic aggregates (Fig. 1a). A notable exception is quartz-rich lithologies with its lower VP/VS ratio of 1.6. This ratio is not, therefore, a very good indicator of lithology, and absolute values of velocities are preferable. Notable trends are those of increasing velocities in the oceanic crust accompanying transition from hydrated gabbros to dry eclogites, and a similar trend of decreasing velocities accompanying hydration (serpentinization) of peridotites. Fully serpentinized rocks have velocities similar to or lower than those of crustal rocks, which results in faint or inverted velocity contrast at the Moho (Bostock, et al. 2002). Anhydrous eclogite velocities are similar to those of dry peridotites, which results in a loss of seismic contrast between the mantle and eclogitic oceanic crust at depths (Abers 2005).
Fig. 1

Seismic velocities of rocks and minerals representative of the various lithologies in subduction zones. a Isotropic sound velocities showing that most rocks except quartzite lie close to VP/VS ratio of √3 or Poisson ratio of 0.25 (solid line). The effect of hydration is to reduce sound velocities (green arrow). A similar trend exists for the transformation of dry eclogite to hydrated gabbro. Lw and gl stand for lawsonite and glaucophane, respectively. b Effect of anisotropy in ultrabasic rocks and pore fluid overpressure (red arrow). Effects of anisotropy are especially marked in foliated serpentinites (Bezacier, et al. 2013; Bezacier, et al. 2010a) with the VS1 branch (full circles) and VS2 branch (crosses) covering a broad range of absolute velocities and VP/VS ratios. A foliated layer of serpentinite can explain the properties of anisotropic layers observed just above the subducting crust of Cascadia (N09, Nikulin, et al 2009). Ultra-low-velocity layers (A09-S09, Audet, et al. 2009, Song, et al. 2009) require pore fluid overpressure (Peacock, et al. 2011). Atg antigorite serpentinite, CPx clinopyroxene, OPx orthopyroxene, and Ol olivine. Olive symbols olivine aggregate and dark green symbols pyroxene-rich peridotite

VP/VS relationship becomes very complex (Fig. 1b) when the large anisotropy typical of hydrated minerals and rocks is taken into account (Bezacier, et al. 2010a; Bezacier, et al. 2010b; Mainprice and Ildefonse 2009). Large seismic anisotropy of hydrated minerals is a primary cause of anisotropy in deformed rocks of subduction zones. In foliated serpentinites, the combination of intrinsic mineral anisotropy due to the layered structure of phyllosilicates and their strong alignment in deformed rocks due to the plate-shaped crystals results in a range of VP/VS ratio spanning most of that of typical subduction zone rocks (Bezacier, et al. 2010a). Anisotropy of blueschists is also marked because of alignment of anisotropic amphiboles and epidotes (Bezacier, et al. 2010b). Absolute velocities and VP/VS ratio are also drastically decreased by the presence of overpressurized fluids (Peacock, et al. 2011). Finally, in addition to modifying absolute velocities and VP/VS ratio, the presence of fluids or magmas damps seismic waves because of fluid motion in porosity and can be tracked by mapping seismic attenuation (Nakajima 2014).

Magnetotellurics

Strong constrains on fluid location is provided by electrical conductivity tomographic images (Baba, et al. 2010; Brasse and Eydam 2008; Brasse, et al. 2009; Ichiki, et al. 2009). Over the last decade, the accuracy and resolution of 2D electrical conductivity images has greatly improved (Wannamaker, et al. 2014; Worzewski, et al. 2011) with imaging of fluid paths that can be compared with seismic tomography. Typical values of conductivity range between 10−3 and 10−4 and 1 S.m 1, the lower values being defined by the background sensitivity in cold and fluid-poor regions, and the highest observed in zones where fluids and melts are abundant.

Laboratory measurements of electrical conductivity of earth-forming materials provide the basis for interpreting magnetotelluric data. Silicates, including both nominally anhydrous and hydrous phases such as serpentines, are poor conductors, with a small polaron-type conduction mechanism that results in high temperature dependence, and typical conductivities lower than 10−3–10−4 S.m−1 at temperatures of the forearc (Guo, et al. 2011; Reynard, et al. 2011). Brucite, a minor component of hydrated ultrabasic rocks, has a slightly higher conductivity, because conductivity occurs mainly by proton exchange (Fujita, et al. 2007), but is not abundant enough to explain high conductivity in hydrated ultrabasic rocks.

High conductivities of the forearc regions require the presence of an interconnected conductive fluid mixed with serpentinized peridotites because high-conductivity solids, iron oxides, sulfides, graphite, and metals are likely not sufficiently abundant to form a connective network (Kawano, et al. 2012; Reynard, et al. 2011). At the low temperatures of the forearc mantle, saline waters are the best candidates for high-conductivity fluids in the absence of melting. NaCl salt is soluble and is carried by fluid inclusions (Vanko 1988) and to a smaller extent by hydrothermal minerals (Ito, et al. 1983; Lécuyer and Reynard 1996) of the subducted lithosphere that was hydrothermally altered by seawater either at the ridge (Spooner and Fyfe 1973) or at the trench (Ranero, et al. 2003). Fluid contents and salinity are obtained by comparing model conductivities of fluid-rock mixtures with observed values in the forearc mantle (Fig. 2). The assumed (resistive) matrix and (conductive) fluid-filled pore geometry is either an assemblage of spheres or a cubic network of fractures, for which exact expressions have been derived (Waff 1974) and were used for calculations. Both models yield virtually identical results that can be approximated by
Fig. 2

Relationships between fluid fraction, salinity, and electrical conductivity of the forearc mantle (modified from Reynard et al., 2011). Electrical conductivity increases from 10−3 to 10−4 S.m-1 (background of MT studies) up to ca. 1 S.m−1 from cold to hot subduction zones due to an increase in salinity of fluids at constant fluid fraction (dashed arrows) or an increase of fluid fraction at constant salinity (solid arrows). Inferred starting fluid composition match that expected for fluids issued by dehydration of altered oceanic crust (dark green shaded area) assuming Cl totally is dissolved in the fluid (Ito, et al. 1983). In Cascadia, the hottest subduction zone, extensive serpentinization is inferred from seismology. Modest values of conductivity around 2 10−2 S.m−1 are observed in Northern Cascadia. They are interpreted as dilution of saline fluids by “flooding” with additional low-salinity water from slab dehydration that are no longer consumed by serpentinization once it has reached completion (full red arrow), or by a decrease of fluid fraction due to fluid migration toward the arc (dashed red arrow, see Fig. 3). Cl content of serpentinites in equilibrium with fluid of a given salinity is calculated assuming a fluid/solid fractionation coefficient of 100 (Scambelluri, et al. 1997)

$$ {\sigma}_b=2/3\ F{\sigma}_f, $$
(1)
where σ b is the bulk aggregate conductivity, F the fluid volume fraction, and σ f the conductivity of the fluid is larger than that of the solid, with a maximum conductivity of 10−4 S.m−1 for serpentinites (Reynard, et al. 2011). Conductivities of saline fluids at high pressure and temperatures (Quist et al. 1968) allow relating fluid conductivity to salinity (Hyndman and Shearer 1989; Reynard, et al. 2011). The simple expression used by these authors has been shown to overestimate slightly conductivity at high salinities, and a more precise salinity-pressure-temperature-conductivity relationship was established from molecular dynamics (Sakuma and Ichiki 2016). Saline fluid conductivity is not very sensitive to temperature and pressure in the range of the forearc mantle (0.5–2 GPa, 573–973 K), and a simple second-order polynomial expression was fitted to experimental (Quist et al. 1968) and molecular dynamics data (Sakuma and Ichiki 2016) with a 30 % precision similar to discrepancies between datasets
$$ \log {\sigma}_f=1.538 + 0.7386 \log m-0.05277{\left( \log m\right)}^2, $$
(2)

where m is the NaCl molality in aqueous fluid.

These relations express the tradeoff between fluid fraction and salinity that cannot be independently determined for a given conductivity (Fig. 2b). The correction to saline fluid conductivities from molecular dynamics data (Sakuma and Ichiki 2016) results in a 50 % increase of maximum salinities with respect to former estimates (Hyndman and Shearer 1989; Reynard, et al. 2011), without affecting substantially their general conclusions because salinities change over more than one order of magnitude.

Highest salinities are limited by salt saturation in water, which is about 6 m for NaCl at ambient conditions, and increases with temperature and pressure. Current measurements are limited to 300 MPa over a narrow temperature range, and were fitted to a polynomial expression (Sawamura, et al. 2007). Extrapolation of this empirical fit is uncertain, but minimum values of 8–12 m are obtained at 300 MPa and 200–700 °C, which are close to the highest values estimated for explaining observed electrical conductivities (Fig. 2). These values are also above measurements of salinity in fluid inclusions from high-pressure ophiolitic rocks (Philippot, et al. 1998; Scambelluri, et al. 1997), indicating that aqueous fluids are likely undersaturated in salt at forearc conditions. The upper bound for fluid fraction is estimated as 3 %, above which the mixture is not dynamically sustainable and would collapse causing fluid escape and release (Richard, et al. 2007). A lower bound of 0.3 % was used in the microscopic model (Fig. 2) because lower fluid fractions would be unlikely to form a connective network (Reynard, et al. 2011). However, at the resolution of magnetotelluric studies of a few kilometers or more, the existence of discrete high-porosity fault network zones separated by large impermeable blocks make lower average fractions of connective fluid realistic.

Discussion

Rock hydration and pore fluids from seismic observations

Simple estimations of the water stored in solids can be attempted if it is assumed that rocks are isotropic in the forearc wedge (Fig. 1a). This is reasonable in first approximation in the forearc mantle that is likely static and cold because of mechanical decoupling near the megathrust (Wada, et al. 2008). At first order, hydration is identified with serpentinization because serpentine is the major stable hydrous mineral under the P-T conditions of the forearc wedge (Ulmer and Trommsdorff 1995). This is also a place where seismic rays used to construct tomographic images are evenly oriented and sample all velocities, a case that is not verified deeper in the slab where anisotropic effects have to be taken into account in petrophysical interpretation of seismic velocities (Reynard, et al. 2010). Seismic velocities indicate forearc mantle serpentinization ranging from less than 10 % to up to nearly 100 % in cold and hot subduction zones, respectively (Hyndman and Peacock 2003; Reynard 2013), resulting in the latter case in the inversion of the velocity contrast at the Moho of the overriding plate (Bostock, et al. 2002). Large-scale hydration of the forearc mantle wedge by water-rich fluids released from the subducting oceanic crust was inferred from kinematic thermal modeling (Peacock 1993; Peacock and Wang 1999), and from experimental studies of dehydration reactions in slabs (Schmidt and Poli 1998). Recent coupled geodynamical-petrological modeling confirms that slab dehydration, hence potential for forearc mantle hydration, is low in cold subduction such as NE-Japan and high in hot subduction such as Cascadia of Shikoku (van Keken, et al. 2011).

Hydration of the forearc mantle wedge is caused by dehydration (or eclogitization) of the oceanic crust. Eclogitization results in the disappearance of the seismic signature of the oceanic crust at depths ranging from about 60 km in hot subduction zones down to about 150–200 km in the coldest subduction zones (Abers 2000; Helffrich and Abers 1997) where hydrated silicate lawsonite with low seismic velocities may be preserved (Chantel, et al. 2012; Reynard and Bass 2014; Schmidt and Poli 1998). Extensive dehydration of the oceanic crust is also associated with seismicity along the main Wadati-Benioff zone (Kita, et al. 2006).

Interpretation of seismic velocities is more complicated if anisotropy is taken into account (Fig. 1b). Several seismological and geological observations require taking into account seismic anisotropy or pore fluid pressure effects. In the mantle wedge near the slab, the presence of deformed serpentinites with foliation parallel to the interface is expected and can contribute to anisotropy (Katayama, et al. 2009). Anisotropic 2–5 km thick low-velocity layers at the top of the slab interface (Nikulin, et al. 2009; Park, et al. 2004) have been interpreted as deformed serpentinites (Bezacier, et al. 2013; Bezacier, et al. 2010a), but they lie at the lowest end of velocity trends in foliated serpentinites (Fig. 1b). Ultra-low-velocity layers have been observed in Cascadia and Mexico, with velocities even lower than that of the lowest ones in foliated serpentine aggregates, and VP/VS ratio up to 2.4 (Audet, et al. 2009; Song, et al. 2009). Ultra-low-velocity layers indicate the presence of overpressured fluids (Audet, et al. 2009; Peacock, et al. 2011; Song, et al. 2009) in what has been identified thus far with the oceanic crust, or at least its upper part. It is possible that a deformed serpentinite or sediment layer saturated with fluid contributes to the ultra-low-velocity layers near the plate interface, but this assumption is difficult to test within the resolution of seismic data. The possible combination of seismic anisotropy of the solid aggregate and of overpressured fluids in cracks (Schubnel, et al. 2006; Song and Kim 2012) makes quantitative estimation of the fluid proportion difficult.

In the serpentinized forearc mantle wedges of hot subduction zones such as Cascadia or Shikoku (Bostock, et al. 2002; Matsubara, et al. 2009; Nakajima, et al. 2009), VP/VS ratios are slightly higher than those expected for isotropic serpentinite, up to 1.85 instead of 1.76 (Bezacier, et al. 2013; Bezacier, et al. 2010a). This may indicate that they are saturated with minor fluid component or have a slight anisotropy. Saturation of serpentinized forearc mantle with fluids is consistent with high conductivities as discussed below, and with high attenuation of seismic waves (Nakajima 2014; Saita, et al. 2015).

Fluid composition from magnetotelluric data

Magnetotellurics made great improvements in providing more accurate pictures of subduction zones from early studies that depicted rough limits between compartments of a few tens of kilometers to recent studies that give resolution of a few kilometers (Wannamaker, et al. 2014; Worzewski, et al. 2011). In the forearc region, the most prominent structures are high-conductivity zones that are located near the limit between the serpentinized mantle and the base of the overriding plate (Fig. 3). Such high-conductivity zones are typical of hot subduction zones and are absent in the cold subduction of the Pacific plate beneath Northern Honshu and Hokkaido in Japan. As argued above, high conductivities in the forearc are interpreted as saline fluids whose fraction and salinity can be estimated from conductivity (Fig. 2).
Fig. 3

Potential location of high-salinity fluids in the forearc mantle and pathways of mixing with hotsprings and the volcanic arc. Magnetotelluric profiles in the Cascadia subduction (Wannamaker, et al. 2014) are shown on the right and are interpreted on the left. The southernmost section shows the highest conductivity in the forearc (green ellipse) that is interpreted as up to 1 m NaCl fluids using diagrams in Fig. 2. Lower forearc conductivities (green ellipses) on the other two sections indicate dilution by more than one order of magnitude by low-salinity dehydration fluids from the slab or a decrease by more than one order of magnitude of the fluid fraction. This is attributed drainage to shallow aquifers above the forearc region (e. g., the Willamette basin in Oregon, WB) or to the volcanic arc (VA) region (green arrows). High-conductivity regions further east are ascribed to melt-rich regions under the volcanic arc (red ellipses)

The range of conductivities observed in several subduction forearc regions shows that cold subduction displays low conductivities typical of low-fluid fractions or salinity, whereas conductivities in hot subduction zones can reach 1 S.m−1 which require high fluid fractions or salinity. Because of the tradeoff between fluid fraction and salinity, two extreme models can explain the observed range of conductivity, one where salinity increases from a few millimeters to a few meters at constant fluid fraction around 1 % (full arrows and filled colored fields, Fig. 2), and one where fluid fraction changes from 10−5 to 1 % at constant high salinity (dashed arrows and dotted fields, Fig. 2).

Consumption of slightly saline fluids from the oceanic crust by serpentinization of the forearc mantle can increase the salinity (or conductivity) of the residual fluid by a factor of up to 30 (Reynard, et al. 2011) at constant fluid fraction (thick green arrows, Fig. 2). Starting salinity of 0.05–0.1 m corresponding a mixture of subducted pore seawater with 6–12 volumes of pure water from dehydration reactions is needed (Reynard, et al. 2011). This estimate is compatible with dehydration of altered oceanic crust yielding fluids with salinity of ~0.03–0.2 m, or of altered oceanic crust and sediments yielding fluids with salinity of ~0.06–0.4 m according to their compositional range (Ito, et al. 1983). Sulfates may also contribute to salinity (Debret, et al. 2014). Salinity increases as the fluids rise and are consumed, reaching its maximum value at the top of the serpentinized forearc mantle, where high conductivity areas are detected by magnetotelluric studies (Wannamaker, et al. 2014; Worzewski, et al. 2011). This hypothesis is supported by the fact that high conductivity are observed in hot subduction zones where serpentinization is also detected from seismology, and not in cold subduction zones where seismic velocities suggest sluggish serpentinization. Increase of salinity due to progressive serpentinization was also reported in high-pressure serpentinites form the Alps (Scambelluri, et al. 1997).

With these assumptions, conductivity should increase in the forearc as the thermal parameter of the subduction zone increases. This is roughly verified since the forearc region of cold Pacific subduction beneath NE-Japan shows low conductivities when compared with hotter subduction zones (Fig. 2). There are, however, notable exceptions to this general trend. For instance, Northern Cascadia, the hottest subduction zone, shows intermediate conductivity, not the highest. This contradiction may be resolved by considering that, as seismic data suggest (Bostock et al., 2002), the Northern Cascadia forearc mantle is already fully serpentinized and “flooded” by low-salinity water from the dehydrating slab. Because serpentinization can no longer consume pure water, the dehydration fluids will dilute the originally enriched residual waters (thick red arrow, Fig. 2). Another possibility is that saline fluids are episodically released from the high-conductivity region, thereby reducing the fluid fraction and the overall conductivity (dashed red arrow, Fig. 2). This release could feed high-salinity fluids to hot spring systems in the forearc region (Hurwitz, et al. 2005; Kusuda, et al. 2014; Masuda, et al. 1985; Nakamura, et al. 2014), or with the volcanic arc (Reynard, et al. 2011). This latter hypothesis can be discussed in light of the most recent magnetotelluric profiles, and of geochemical evidences from magmatic inclusions in arc volcanic rocks (Wallace 2005).

Conclusions

Geometry of fluid circulation and links with hot springs and the volcanic arc

Aqueous fluids are produced from the top of subducting plate (sedimentary cover, oceanic crust, hydrated mantle) by compaction of fractures and porosity, and by thermally induced dehydration reactions of minerals (Iwamori 1998; Peacock 1993; van Keken, et al. 2011). Vertical rise of the low-density fluids can be slowed down, impeded, or diverted by permeability barriers. Sediments like clay are well known for providing such barriers, and at depth, phyllosilicates of the clay, mica, and serpentine groups are abundant candidates for providing similar barriers. During ascent, aqueous fluids are also partly used for forming hydrated minerals (Peacock 1993).

Ultra-low-velocity layers are interpreted as overpressured fluids in portions of the oceanic crust at depths near the seismic to aseismic transition on the subduction megathrust (Audet, et al. 2009; Song, et al. 2009). The presence of foliated phyllosilicate layers with low permeability could seal the interface between the slab and the overriding plate and account for this observation. It has been shown that foliated serpentine has anisotropic permeability that could focus fluid flow parallel to the slab up to the tip of the forearc mantle wedge (Kawano, et al. 2011). The plate interface could also be sealed by precipitation of solutes such as silica, and episodically opened by large seismic events, as suggested for Cascadia (Hyndman, et al. 2015) and other subduction zones (Audet and Burgmann 2014). The presence of fluids in the subducting oceanic crust is also suggested by high-conductivity anomalies parallel to the slab (Wannamaker, et al. 2014), and is substantiated by extensive geochemical investigations of high-pressure ophiolitic terranes (Bebout and Penniston-Dorland 2016; Deschamps, et al. 2013). Also, a consequence of salt enrichment in fluids due to hydration reactions such as serpentinization is that rocks such as serpentinites from high-pressure ophiolitic sequences should present relatively high Cl concentrations (up to several hundred or thousand ppm, Fig. 2) according to estimated water-rock partition coefficient (Scambelluri, et al. 1997).

Concentration of high-conductivity fluids at the tip of the serpentinized mantle wedge or at the base of the overriding plate is imaged in 2D electrical conductivity profiles of various subduction zones (Wannamaker, et al. 2014; Worzewski, et al. 2011). Anomalies in the Cascadia subduction profiles (Wannamaker, et al. 2014) are tentatively interpreted in terms of salinity and fluid fraction (Fig. 3), bearing in mind the tradeoff between these quantities discussed above. The highest conductivities requires fluids with salinities of the order of or above that of seawater, which can be provided by fluid release from the slab and salt enrichment by serpentinization or other partial hydration reactions (Reynard, et al. 2011). Current reports show a large range of Cl concentration in serpentinites from subduction context, suggesting interactions with high-salinity fluids at various levels (Deschamps, et al. 2013; Deschamps, et al. 2010; Lafay, et al. 2013; Scambelluri, et al. 2004; Scambelluri, et al. 1997). Cl concentrations in serpentinites that equilibrated with up to 12 m NaCl fluids should vary in the range 20–5000 ppm (Fig. 2) assuming a partition coefficient of 100 between fluids and rocks (Scambelluri, et al. 1997). Serpentinites interacting with large amounts of dehydration fluids close to the subduction interface should have low Cl content (20–100 ppm) while those of the forearc mantle should have a range of concentrations up to several thousand ppm. Obtaining Cl concentrations in serpentinites from in situ forearc context (Savov, et al. 2005) or from exhumed forearc (Deschamps, et al. 2010) could help resolve this issue.

Geochemical evidence for saline fluids of deep origins is found in hot springs of the forearc region of subduction zones (Hurwitz, et al. 2005; Kusuda, et al. 2014; Masuda, et al. 1985; Nakamura, et al. 2014). He isotopic compositions of hydrothermal waters from the Arima district in Japan suggest interactions with the forearc mantle (Kusuda, et al. 2014), which I tentatively ascribe to serpentinization reactions, although this interpretation is not favored by the authors of the study. Whatever the case, brines mixed with meteoritic waters in hot springs are the most direct evidence of deep saline aquifers in the forearc region above the serpentinized mantle and the region where tremors are observed. Possible fluid paths between deep conductive fluids at the top the forearc or at the base of the overriding plate and shallower aquifers are highlighted as green arrows (Fig. 3) in the magnetotelluric profiles of Cascadia (Wannamaker, et al. 2014). Such paths can explain the saline brine signature in waters of the Willamette basin above the forearc of the EMSLAB profile in Oregon (Hurwitz, et al. 2005), and over whole Cascadia ranges (Mariner, et al. 1990). The observation of hot springs with salinities of about 0.1 m suggests that fluids of high salinity (0.3–1 m, Fig. 3) mixed with 3–10 volumes of dilute meteoritic waters.

Connections between deep saline fluid reservoirs at the top of the serpentinized mantle or at the base of the overriding plate and the volcanic arc are also suggested by the magnetotelluric CAFE-MT and EMSLAB profiles of Cascadia (Wannamaker, et al. 2014). Sharp high-conductivity anomalies suggest saline brines rise from the conductive anomalies of the mantle wedge to the arc through the crust following a structure dipping westward at about 30° (Fig. 3). These structures may correspond to a major fracture or fault zone, and fluid discharge to the arc could account for the lower conductive anomalies in these profiles than in the southernmost KLM-MDC profile where no such structure is observed (Wannamaker, et al. 2014). This observation supports the hypothesis of mixing of magmas with deep saline waters (Reynard, et al. 2011) to explain the high Cl/H2O ratios in magmatic inclusions of volcanic rocks from arc magmas. High Cl/H2O ratios of magmatic inclusion require the addition of Cl-rich fluids from the serpentinized wedge (Straub and Layne 2003). Fluids with salinities in the range 0.2–12 m from the cold mantle wedge (Fig. 2) account for the range of Cl/H2O ratios in magmatic inclusions up to 30 wt% equivalent NaCl, and shallow separation of saline brines due to immiscibility is required to explain the highest salt concentrations near 50 wt% (Wallace 2005).

Declarations

Acknowledgements

The author is grateful to the JpGU for invitation to publish this review, to the LABEX Lyon Institute of Origins (ANR-10-LABX-0066) of the Université de Lyon for its financial support within the program “Investissements d’Avenir” (ANR-11-IDEX-0007) of the French government operated by the National Research Agency (ANR). This work was also supported by “Programme National de Planétologie” of the “Institut National des Sciences de l’Univers”, CNRS. Careful comments by two anonymous reviewers and BO Mysen helped in improving the manuscript. PE Wannamaker kindly provided the magnetotelluric profiles used in Fig. 3.

Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

Authors’ Affiliations

(1)
Laboratoire de Géologie de Lyon, CNRS, Ecole Normale Supérieure de Lyon, Site Monod
(2)
Université Claude Bernard Lyon 1

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