Fig. 5

Position of the 29Si NMR Q4 peak as a function of bulk TiO2 content of the glasses for NS4 (blue) and NS8 (black) compositions. The systematic shift in frequency is likely due to the continuous growth of an additional Q4 peak due to [4]Ti nearest-neighbor interactions with Q4 Si. Peak fitting of the spectra was performed using Gaussian peaks, with fit iterations converging at a chi-squared tolerance value of 1E-6